화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 촉매_포스터
제목 Graphene Oxide Substituted with N-Heterocyclic Carbene-Palladium Catalyst for Efficient Suzuki Coupling Reaction in Water.
초록 Graphene oxide (GO) has carbonyl and carboxyl functional groups at the edges which bring about unique physicochemical properties. Due to easy functionalization and large surface area, GO is appropriate for being used as a catalytic support. To immobilize palladium on the GO, we used N-heterocyclic carbene (NHC) ligand that has been widely used to improve the stability of metal catalyst. We confirmed that the GO functionalized with NHC ligand was well coordinated with palladium (Pd) acetate. The GO-NHC-Pd complex showed remarkable catalytic activity in the Suzuki reaction of 4-chlorotoluene and phenyl boronic acid in water, under mild condition (1hr, 50℃).
저자 이윤식, 김영오, 최서경
소속 서울대
키워드 suzuki coupling reaction; graphene oxide(GO); N-heterocyclic carbene(NHC); palladium catalyst
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