| 학회 | 한국고분자학회 |
| 학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 | 27권 2호, p.218 |
| 발표분야 | 특별 심포지엄 |
| 제목 | Synthesis of Poly(phenylene oxide)s Containing Trifluoromethyl Groups via Sequential Nucleophilic Aromatic Substitution Reaction |
| 초록 | The controlled construction of poly(phenylene oxide) (PPO) backbone which only consists of phenyl rings and ether linkages has been a great challenge in the field of polymer synthesis. In this study, as a novel synthetic method for poly(phenylene oxide)s, sequential nucleophilic aromatic substitution reaction was investigated. Several new poly(phenylene oxide)s containing pendent trifluoromethyl groups (CF3-PPOs) were synthesized by nucleophilic aromatic substitution (SNAr) reaction of the monomer containing fluoro and nitro leaving groups (BC type monomer) with hydroquinone, 4,4'-dihydroxydiphenyl ether, and biphenol (AA type monomer), respectively. Based on the leaving and activating characteristics of the nitro group, the polymerization reaction was carried out in a sequential manner-the preferential fluorine displacement reaction followed by the nitro displacement reaction. The synthesized high molecular weight polymers (CF3-PPOs) were amorphous and dissolved well in a wide range of organic solvents. Details of the polymerization, structures and properties of the polymers will be presented. |
| 저자 | 김윤준, 정임식, 김상율 |
| 소속 | 한국과학기술원 화학과 분자과학사업단 (BK21) & 기능성고분자연구센터 |
| 키워드 | Poly(phenylene oxide); Sequential Nucleophilic Aromatic Substitution |
