화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 정밀화학_포스터
제목 Ag nanoparticles onto thin silica coating of graphene oxide for SERS substrate
초록 Ag nanoparticles onto thin silica coating of graphene oxide for SERS substrate was prepared and used an as a surface-enhanced Raman scattering (SERS) substrate. Graphene oxide was coated with silica layer on their surface by using physical absorption of sodium silicate as a binder combine with sol-gel process of of 3-mercaptopropyl trimethoxysilane. The thickness of silica is ~6 nm. Ag NPs were embedded on the silica-coated graphene oxide by the reduction of Ag+ by octylamine in the presence of ethylene glycol to prepare GO@SiO2@Ag. The Raman signal of GO@SiO2@Ag was 1.8-fold as strong as than that of GO without a silica coating. For application, the GO@SiO2@Ag was applied to detect 4-mercaptobenzoic acid (4-MBA). The limit of detection of 4-MBA was 0.74 μM, indicating that the GO@SiO2@Ag can be utilized as a highly sensitive SERS substrate for detection of trace amounts of chemicals in various fields.
저자 하유나, 함은일, 강은지, 김태용, 김형모, 전봉현
소속 건국대
키워드 Ag nanoparticle; Surface-enhanced Raman scattering; Graphene oxide; 4-mercaptobenzoic acid
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