화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.1329
발표분야 촉매 및 반응공학
제목 Catalytic Activity of monomer Chiral Salen Complexes encapsulated in Meso Silicate
초록 Silicate was modified by alkaline and acidic solution to introduce mesoporosity in the crystals. Heterogenized salen complexes was prepared in the mesopores of silicate by ‘ship-in-a-bottle’ method. Hydrolytic kinetic resolution (HKR) and Phenol kinetic resolution (PKR) of racemic terminal epoxides was performed successfully by using chiral (salen) catalysts encapsulated in meso silicate.
저자 곽소봉, 김용석, 카테라 라울, 김건중
소속 인하대
키워드 Meso Silicate; Ship-in-a-bottle; encapsulation; HKR; PKR
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