학회 |
한국화학공학회 |
학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
권호 |
14권 1호, p.1329 |
발표분야 |
촉매 및 반응공학 |
제목 |
Catalytic Activity of monomer Chiral Salen Complexes encapsulated in Meso Silicate |
초록 |
Silicate was modified by alkaline and acidic solution to introduce mesoporosity in the crystals. Heterogenized salen complexes was prepared in the mesopores of silicate by ‘ship-in-a-bottle’ method. Hydrolytic kinetic resolution (HKR) and Phenol kinetic resolution (PKR) of racemic terminal epoxides was performed successfully by using chiral (salen) catalysts encapsulated in meso silicate. |
저자 |
곽소봉, 김용석, 카테라 라울, 김건중
|
소속 |
인하대 |
키워드 |
Meso Silicate; Ship-in-a-bottle; encapsulation; HKR; PKR
|
E-Mail |
|
원문파일 |
초록 보기 |