화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 에너지변환 및 저장시스템(분자전자 부문위원회)
제목 Effect of Chemical Structure of Additives on the Performance of Organic Solar Cells
초록 Post-treatment is one of the problems to commercialize the organic solar cells because of the low reproducibility. The additive approach allows annealing-free system because they can control the nanoscale morphology without post-treatment. The additives must have higher boiling point than main solvent and different solubility between donor and acceptor. However, these two requirements are not enough to explain all of phenomena. Here, we studied the effect of chemical structure and amount of additives on phase separation of photoactive layers. We synthesized new types of small molecule additives which have similar chemical structures to that of donor and acceptor. These additives are compared with well-known additives structurally not similar to donor and acceptor. At the result, all additives have higher boiling points are effective regardless of chemical structures. The rate of morphology formation may be controlled according to the chemical structures and the amount of additives.
저자 심치영, 박종환, 심명선, 이지황, 김종수, 김주현, 조길원
소속 포항공대
키워드 Organic Solar Cell; Additive
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