화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 가을 (10/13 ~ 10/14, 제주 ICC)
권호 30권 2호
발표분야 고분자 구조 및 물성
제목 Stimuli-Responsive Gels from Reversible Coordination Polymers
초록 The aqueous gels from the coordination polymers were observed to transform rapidly into the fluid solutions with counteranion exchange. This reversible sol-gel interconversion in response to external stimuli is attributed to depolymerization or transformation of the folded helical conformation into an unfolded zigzag conformation of the coordination chains with counteranion exchange. These results represent a significant example that size change of the entrapped guest in self-assembling system can provide a useful strategy to create stimuli-responsive smart nanomaterials with functions that can be produced at any time on demand.
저자 김호중, 이명수
소속 연세대
키워드 stimuli-responsive; gel; coordination polymer
E-Mail