| 학회 |
한국고분자학회 |
| 학술대회 |
2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 |
30권 1호, p.310 |
| 발표분야 |
유기반도체 |
| 제목 |
Syntheses and light-emitting properties of new PPV derivatives containing polyhedral oligomeric silsequioxane |
| 초록 |
A new light-emitting poly(p-phenylenevinylene) (PPV) derivative containing a polyhedral oligomeric silsequioxane (POSS-PPV) and its MEH-PPV copolymers, [Poly(POSSPV-co-MEHPV)]s, have been synthesized through the Gilch polymerization, and their light-emitting properties were investigated. The synthesized polymers were characterized by NMR, GPC, thermogravimetric and elemental analysis. The POSS-PPV and copolymers showed almost the same optical properties as the MEH-PPV, regardless of copolymer composition. The POSS-PPV and MEH-PPV all showed their peak absorption at 505 and 496nm, and PL emission maxima at 578 and 581nm. POSS-PPV showed higher PL quantum efficiency than the MEH-PPV. Synthesis, characterization and electroluminescent properties of the polymers will be presented. |
| 저자 |
강종민1, 이종희2, 조훈제2, 심홍구2, 황도훈1
|
| 소속 |
1금오공과대, 2한국과학기술원 |
| 키워드 |
polyhedral oligomeric silsequioxane PPV derivative electroluminesence |
| E-Mail |
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