| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터) |
| 권호 |
14권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Polymerization of 3-Ethynylaniline by Transition Metal Catalysts |
| 초록 |
Here,we report the research results on the synthesis of a new polyacetylene with amine functional groups and the elucidation of the electro-optical and electrochemical properties of the resulting conjugated polymer. The polymerization of amine-containing acetylene monomer by using various transition metal catalysts proceeded well in homogeneous manner to give a relatively high yield of polymer. The polymer structure was characterized by various instrumental methodsto have the conjugated backbone system with the designed functional groups. The absorption spectrum starts around 700 nm, which is due to the π→ π* interband transition of these conjugated polymer system. This polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. |
| 저자 |
제갈영순1, 진성호2
|
| 소속 |
1경일대, 2부산대 |
| 키워드 |
Polyacetylene; conjugated polymer; ethynylaniline; synthesis; characterization
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| E-Mail |
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