| 학회 | 한국화학공학회 |
| 학술대회 | 2004년 봄 (04/23 ~ 04/24, 공주대학교) |
| 권호 | 10권 1호, p.596 |
| 발표분야 | 에너지/환경 |
| 제목 | Kinetics for Degradation of Polystyrene in Supercritical Fluids |
| 초록 | It was discussed the kinetic behavior of degradation of polystyrene in supercritical fluids. n-hexane and water were employed as a supercritical solvent. The degradation of PS in supercritical n-hexane and water as well as the thermal pyrolysis was presumed to follow the first-order reaction kinetics in the initial stage of the reaction. From the Arrhenius plots, the activation energies were evaluated to be 224 kJ/mol for the thermal pyrolysis and 140 kJ/mol for the degradation in supercritical n-hexane. It was apparent that the degradation in supercritical n-hexane can take place at lower temperatures than the thermal pyrolysis. The activation energy of degradation using supercritical water was also compared with that of degradation in supercritical n-hexane and thermal pyrolysis. |
| 저자 | 신희용, 한동일, 곽 현, 배성렬 |
| 소속 | 한양대 |
| 키워드 | kinetic; degradation; supercritical fluid |
| 원문파일 | 초록 보기 |
