화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 분자전자 소재 및 소자 기술(분자전자 부문위원회)
제목 Use of triplet state exciton to organic solar cell
초록 Organic solar cells can be very attractive energy sources because of low cost, light weight, large area, and mechanical flexibility. The efficiency of photoinduced charge separation is most crucial in determining the overall device efficiency in organic solar cells. To achieve high power conversion efficiency, long exciton diffusion length is required for donor-acceptor heterojunction to affect efficient charge separation. The diffusion length of singlet state excitons in photovoltaic materials is, however, usually several nm. On the other hand, the lifetime of triplet state excitons is much longer than singlet state excitons because of spin-forbidden direct back electron transfer by intersystem crossing. In order to use triplet state exciton to organic solar cell, the phosphorescent materials were doped to conjugated polymer.
저자 윤상준, 이행근, 박오옥
소속 한국과학기술원
키워드 photovoltaic; triplet exciton; diffusion length
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