| 학회 | 한국화학공학회 |
| 학술대회 | 2005년 가을 (10/21 ~ 10/22, 인하대학교) |
| 권호 | 11권 2호, p.2570 |
| 발표분야 | 재료 |
| 제목 | Synthesis of conjugated polymer - mesoporous TiO2 nanocomposite particle and thin film |
| 초록 | Synthesis of conjugated polymer-TiO2 nanocomposites has been attracted for their useful applications in optoelectronic devices, such as solar cells, electrochromic devices, light-emitting diodes, and charge-storage devices, which make a heterojunction between organic and inorganic semiconductors where charge transfer occurs. In this study, we propose a new method to obtain a porous nanocomposite of conjugated polymer and TiO2 by a direct polymerization of conjugated polymer in the mother solution of mesoporous TiO2. We prepared two types of nanocomposites, core-shell nanoparticles of polymethineimine and mesoporous TiO2, and nano-sized polypyrrole embedded mesoporous TiO2 thin film. Core-shell nanoparticles of polymethineimine and mesoporous TiO2 were synthesized using TiCl4 as a catalyst for the polymerization of polymethineimine and as a precursor of TiO2. And nano-sized polypyrrole embedded mesoporous TiO2 thin films were synthesized using sonochemical polymerization of pyrrole in the mother solution of mesoporous TiO2 thin film. |
| 저자 | 장광석, 양희만, 김종득 |
| 소속 | 한국과학기술원 생명화학공학과 |
| 키워드 | mesoporous; nanocomposite; polypyrrole |
| 원문파일 | 초록 보기 |
