| 학회 |
한국화학공학회 |
| 학술대회 |
2003년 봄 (04/25 ~ 04/26, 순천대학교) |
| 권호 |
9권 1호, p.1020 |
| 발표분야 |
재료 |
| 제목 |
Synthesis of Polynuclear Cluster Compounds Derived from Polyynedily and Polyynyl Iron Complexes |
| 초록 |
Transition metal complexes with hyper-conjugated carbon bridge as a ligand have attracted much attention from various viewpoints. Our attention has been focused on polynuclear complexes from the linear complexes, M-(C≡C)n-M, and a polynuclear C2-based complexes has been established as a results of synthetic study starting from the ethynyl and ethynediyl complexes. Here, we disclose the reaction of polyynyl and polyynediyl complexes with di- and trinuclear species produces polycarbon-polymetal systems with a variety of coordination structures including η2-alkyne, μ-acetylide, μ-cumulenylidene, μ-alkylidyne and μ3-propargylidene structures. |
| 저자 |
정민철1, 사쿠라이 아이조2, 아키타 무네타카2
|
| 소속 |
1국립순천대, 2동경공업대 |
| 키워드 |
Iron; Polynuclear; Polyynedily; Polyynyl
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| E-Mail |
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