| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Nanohybridized Electrolytes Containing Silver Nanoparticles for Facilitated Olefin Transport |
| 초록 |
Silver ions and metallic nanoparticles have been successfully used as olefin carriers for olefin/paraffin separation. In chapter 1, it was observed that the separation performance for propylene/propane mixtures deteriorated with time because of the reduction of silver ions. The reduction reaction was prohibited by introducing strongly interactive functional groups with silver ions such as phthalate groups. Thus the interaction of phthalate groups of poly(ethylene phthalate) with silver ions has been elaborated. In chapter 2, a new application of silver nanoparticles as a novel olefin carrier was explored. The surfaces of silver nanoparticles were chemically activated using p-benzoquinone as electron acceptor. The surface positive charge was confirmed by the increase in binding energy of the silver nanoparticles with increasing silver content. It is thus expected that the chemically activated surface may form complexes with olefin molecules resulting in facilitated olefin transport. |
| 저자 |
강상욱1, 차국헌1, 김종학2, 강용수3
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| 소속 |
1서울대, 2연세대, 3한양대 |
| 키워드 |
silver ion; silver nanoparticle; ionic liquid; facilitated transport and membrane
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| E-Mail |
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