| 학회 | 한국공업화학회 |
| 학술대회 | 2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
| 권호 | 18권 2호 |
| 발표분야 | 정밀화학-포스터 |
| 제목 | A Novel Diazide Monomer and Dialkyne Monomer for Click Chemistry |
| 초록 | Click chemistry is powerful strategy relies mainly upon the construction of carbon-geteroatom bonds. “Click” chemistry has nowadays also been introduced in dendrimer and polymer synthesis and utilized to cross-link block copolymer vesicles. Extremely high yields (usually above 95%) are combined with a high tolerance of functional groups and reactions running at moderate temperatures (25°C - 70 °C). In this study, we desinged novel difunctional monomer for azide/alkyne click chemistry. α,α‘-Dichloro-p-xylene was converted into diazide monomer in the presence of NaN3/Acetonitrile at 78℃ and Sulfonyl diphenol was converted into dialkyne monomer in the presence of propagyl bromide/THF at R.T..Characterization by NMR spectruscopy, Elemental analysis, Gas Chromatography, FT-IR. |
| 저자 | 박샛별, 이범재 |
| 소속 | 충남대 |
| 키워드 | Click Chemistry; Azide monomer; Alkyne monomer |
