| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 봄 (04/11 ~ 04/12, 연세대학교) |
| 권호 |
28권 1호, p.8 |
| 발표분야 |
특별 심포지엄 |
| 제목 |
Living Polymerization of N,N-Diphenyl Acrylamide with Triisobutyl Aluminum |
| 초록 |
N,N-diphenyl acrylamide was polymerized in a living fashion with triisobutyl aluminum. The polymerization results showed the increase of molecular weight proportional to the monomer consumed and first-order kinetics with respect to monomer concentration. The increase of molecular weight was also observed with sequential addition of additional monomer. The intermediates obtained under condition of high initiator concentration, revealed that the mechanism involves initiation through 1,4-addition by hydride transfer and propagation by aluminum-oxygen bond interchange. Details of polymerization and its mechanism will be presented. |
| 저자 |
김연규;김상율 |
| 소속 |
한국과학기술원 화학과 분자과학사업단 (BK21) & 기능성고분자연구센터;한국과학기술원 화학과 분자과학사업단 (BK21) & 기능성고분자연구센터 |
| 키워드 |
living; polymerization; aluminum; acrylamide; group transfer
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| E-Mail |
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