초록 |
One of hot issues for light-transduction devices such as organic solar cells and image sensors, is the development of novel π-conjugated materials which can efficiently absorb the visible photons from solar light. Along this line, Porphyrin chromophore is one of promising candidate due to its extensive two-dimensional π-conjugated system. Here we report on the synthesis of novel terpyridine-functionalized porphyrin derivatives and its polymeric products formed by metal-ligand complexation. All compounds were fully characterized by using 1H-NMR, GPC, MALDI-TOF-MS. To probe photophysical properties of porphyrin polymer spectroscopic measurements containing UV-vis absorbtion and emission spectra have been performed. |