화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.1939
발표분야 열역학
제목 Phase behavior for the binary mixture of methyl methoxyacetate and methyl 3-methoxyacrylate in supercritical carbon dioxide
초록 In this work, the solubility behavior for the (CO2 + methyl methoxyacetate) and (CO2 + methyl 3-methoxyacrylate) mixtures at pressures from (5 to 20) MPa and various temperatures (313.2, 333.2, 353.2, 373.2 and 393.2 K) are measured in the static method with a variable-volume high pressure view cell. The experimental results obtained in this research are correlated with Peng-Robinson equation of state and van der Waals one-fluid mixing rule containing two adjustable interaction parameters. The critical constants for the Peng-Robinson equation of state were estimated using the group contributions method. The Lee-Kesler method was used to predict the acentric factor.
저자 최상원, 천단비, 변헌수
소속 전남대
키워드 Methyl methoxyacetate; Methyl-3-methoxyacrylate; Carbon dioxide; Solubility curves; High pressure phase behavior
E-Mail
원문파일 초록 보기