학회 | 한국화학공학회 |
학술대회 | 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터) |
권호 | 20권 1호, p.43 |
발표분야 | 고분자 |
제목 | Preparation and characterization of poly(methyl methacrylate) derivatives having self-healing properties through the thermally reversible Diels-Alder reaction. |
초록 | In this study, we synthesized the furan-functionalized copolymer for self-healing materials. The furan monomer(furoyl ethyl ether methacrylate, FEEMA) obtained from the reactions between furoyl chloride and 2-hydroxy ethyl methacrylate was copolymerized with ethylene glycol methyl ether methacrylate (EGMA) with various feed ratio to show the effect of furan group on self-healing property. Also 1,1'-(methylenedi-4,1-phenylene)bismaleimide is used as a cross-linker for thermally reversible Diels-Alder reaction. The stable film could be obtained within the specific range of ratio between furan group in copolymer and crosslinker, which shows the self-healing property. |
저자 | 변금섭1, 최소원1, 최원재2, 이종찬2, 차상호1 |
소속 | 1경기대, 2서울대 |
키워드 | free radical polymerization; self-healing; re-mendable; furan; Diels-Alder reaction |
원문파일 | 초록 보기 |