화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.1657
발표분야 분리기술
제목 Photovoltaic properties of quasi-solid state dye-sensitized solar cells using polymer electrolyte adding liquid electrolyte
초록 The addition of the liquid electrolyte to polymer electrolyte based on poly(ethylene-co-methyl acrylate), LiI, and I2 by ‘casting-injection method’ increased the ionic conductivity due to the good interfacial contact between polymer electrolyte and dye molecule, which result in increased cell efficiency. The polymer electrolyte adding liquid electrolyte exhibited the conductivity of 9.33 × 10-3 Scm-1 (at room temperature), higher than the polymer electrolyte without liquid electrolyte. A quasi solid-state dye-sensitized solar cell employing the polymer electrolyte with liquid electrolyte gives an open-circuit voltage of 0.68 V, a short-circuit current of 3.19 mAcm-2 and an energy conversion efficiency of 2.2 % under light intensity of 45 mWcm-2. These result shows that ionic conductivity and cell efficiency can be improved by ‘casting-injection method’ used in this study.
저자 박경희, 박동원, 최용국, 김태영, 김승재, 조성용, 구할본
소속 전남대
키워드 Poly(ethylene-co-methyl acrylate); gel polymer electrolyte; quasi-solid state dye-sensitized solar cells
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