| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Propylene/1-hexene copolymerization using various nano-space confined metallocene Polypropylene catalyst |
| 초록 |
Metal–Organic Frameworks (MOFs) are crystalline open network structures built up by the assembly of discrete metal cations or clusters of metal cations. The highly ordered pore and/or channel structures of MOFs offer novel opportunities to prepare ordered arrays of functional molecules and clusters. In this study, metallocene Polypropylene catalyst with methylaluminoxane (MAO) as cocatalyst was synthesized using different supports, namely MIL-53 (Al) (nanoporous MOF), SBA-15 (mesoporous), and amorphous silica. The metallocene PP catalyst was used in propylene-hexene copolymerization. The effect of nano-space on the catalyst performance, and polymer morphology was investigated. |
| 저자 |
Ann Charise Cariño, 이정숙, 고영수
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| 소속 |
공주대 |
| 키워드 |
metal-organic framework; polypropylene; metallocene catalyst; copolymerization; nano-space
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| E-Mail |
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