화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 고분자합성
제목 Synthesis and characterization of graphene/polyethylene nanocomposites prepared by graphene/(n-BuCp)2ZrCl2 system
초록 In this study, we achieved the production of graphene/polyethylene (PE) composites by the in situ polymerization with (n-BuCp)2ZrCl2 immobilized onto the graphene. The graphene/(n-BuCp)2ZrCl2 system can produce a very higher molecular weight graphene/PE composite nanosheet due to the electronic and steric effects of graphene. Graphene plays a role not only as a support for adsorption, but also as an additional ligand with strong electron donation to (n-BuCp)2ZrCl2 during ethylene polymerization.
저자 이정숙, 고영수
소속 공주대
키워드 ethylene polymerization; graphene/polyethylene nanocomposites; metallocenes
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