| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
분자전자 부문위원회 Ⅰ,Ⅱ |
| 제목 |
An Isomer-free and Low-lying Energy Level Quinoidal Conjugated Polymer with Flat Thiophene Derivative Unit |
| 초록 |
The development of isomer-controllable core containing quinoid materials has been considered as a main issue since the presence of geometrical isomers limits the systematic investigation of their chemicophysical properties. In this work, the isomer-free and low-lying energy level quinoid molecule bQuPheDOT was designed, then a quinoidal conjugated polymer PbQPheDOT-2FT2 was synthesized by using bQuPheDOT monomer. It was found that the prepared quinoid monomer bQuPheDOT exhibited only (Z, E, Z) single isomer configuration, accomplished by steric hindrance between aryl rings and electrostatic intramolecular interaction. The employment of phenyl rings in quinoid core had effects on decrease of the electron-releasing mesomeric effect into conjugated backbone as well as the enhancement of molecular packing. We will explain the effect of the introducing phenylene unit in quinoid core in relation to optical, electrochemical and charge transport properties for quinoidal polymers. |
| 저자 |
최연수, 김윤슬, 문이나, 황경태, 양동성, 한나라, 김동유
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| 소속 |
광주과학기술원 |
| 키워드 |
quinoid conjugated polymer; isomer-free; synthesis
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| E-Mail |
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