| 학회 |
한국화학공학회 |
| 학술대회 |
2016년 봄 (04/27 ~ 04/29, 부산 BEXCO) |
| 권호 |
22권 1호, p.1096 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Dehydrogenative decarbonylation of primary alcohols using efficient heterogeneous PdO@Silica nanocatalyst |
| 초록 |
A solid supported nanocatalyst of palladium oxide and silica nanoparticles (PdO@SNP) was applied successfully for the decarbonylation of verity of primary alcohols. The reaction is believed to proceed by two consecutive organometallic transformations that are catalyzed by the single PdO@SNP nanocatalyst in one pot at relatively lower temperature and absence of the co-catalyst. The dehydrogenation of alcohols was followed by the decarbonylation of aldehydes to produce the products with one less carbon atom. The benzylic, allylic and aliphatic alcohols were selectively catalyzed with PdO@SNP to produce the desired products with high yields. Leaching was not observed and PdO@SNP nanocatalyst can be applied for several times. |
| 저자 |
Nyanzi Joseph1, Muhammad Asif Husain1, 김현빈2, 석승환2, 김도현2, 김정원1
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| 소속 |
1강원대, 2KAIST |
| 키워드 |
비균질촉매 |
| E-Mail |
|
| 원문파일 |
초록 보기 |
