| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
2D-LC analysis of theta-shaped polystyrene prepared by ATRP and “click” chemistry |
| 초록 |
Cyclic polymers have been attracting interest due to their distinct physical properties compared with linear polymers. Theta-shaped polystyrene (PS) was prepared by atom transfer radical polymerization (ATRP) and “click” chemistry. Precursor, 3 arm star PS with terminal azide groups, was prepared by ATRP using a trifunctional initiator and subsequent azidation. The theta-shaped PS was synthesized by “click” chemistry between the 3-arm PS precursor and trialkyne coupling agent. The synthesis of the theta-shaped PS also produced, byproducts of various branched PS. Two-dimensional liquid chromatography (2D-LC) is an effective method for characterization of complex polymers. It is a combination of two LC separation methods such as interaction chromatography (IC) and SEC. In this work, we analyzed theta-shaped PS and their byproducts with 2D-LC of IC ⅹ SEC. |
| 저자 |
김기현1, 장태현1, 백현종2, 정종화2, 이수경2
|
| 소속 |
1POSTECH, 2부산대 |
| 키워드 |
theta-shaped PS; ATRP; 2D-LC
|
| E-Mail |
|
