화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 고분자 합성
제목 Active palladium-based bimetallic catalyst for polymerization of norbornene derivatives
초록 The norbornene-addition polymer displays a characteristic rigid random coil conformation, shows restricted rotation about the main chain, and exhibits strong thermal stability, excellent dielectric properties, optical transparency and unusual transport properties. Therefore, norbornene-addition polymer and its derivatives are attractive materials for the manufacture of microelectronic and optical devices. The palladium complexes were investigated as catalysts for the vinylic polymerization of norbornene using methylaluminoxane (MAO) as a cocatalyst. These palladium-based bimetallic catalyst display very high activities in the norbornene(bicycle[2,2,1]hept-2-ene) polymerization.
저자 김진혁, 김일, bijal. K. B, 하창식, 박대원
소속 부산대
키워드 norbornene; bimetallic catalyst
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