| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
유기전자소자용 소재 및 소자(분자전자소재 부문위원회) |
| 제목 |
Surface modification of Zinc oxide nanorods with Zn-porphyrin via metal-ligand coordination for polymerpotovoltaic applications |
| 초록 |
Fine ZnO nanorods with a length of 120 nm and a diameter of 15 nm were synthesized by using two-step solvothermal route in which ZnO nanoparticle seeds were first prepared in alcohols, followed by nanorods growth in an aqueous reactor. To modify ZnO surface, butanethiol was first utilized for encapsulation ZnO nanorods composed of a thiol-Zn-thiol complex, and metal-ligand axial coordination approach was performed using Zn-porphyrin and nitrogenous ligands possessing thiols. Spectroscopic characterization suggested that the dye-modified ZnO nanorods could be suitable for n-type materials in polymer-based solar cells, forming an organic-inorganic hybrid structure. |
| 저자 |
구재홍, 박주현, 조진주, 이예빈, 김정태
|
| 소속 |
중앙대 |
| 키워드 |
zinc oxide nanorods; photovoltaic applications; porphyrin
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| E-Mail |
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