초록 |
Conducting polymer/cellulose composite papers were obtained through the vapor deposition polymerization of pyrrole monomer on cellulose substrate. Polar and non-polar solvents were introduced into the polymerization process as co-vapors to examine their effect on the major structure and properties of the resulting composite papers. Interestingly, the conductivity of the composite papers increased in the presence of polar co-vapors due to the enhanced orientation of the deposited polymer chains. Some non-polar co-vapors increased the effective surface area of the composite papers, which resulted in an increased specific discharge capacitance. As a result, various co-vapors can be used to tailor the structure and properties of deposited polymers during vapor-phase polymerization. |