| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
| 권호 |
18권 2호 |
| 발표분야 |
고분자-포스터 |
| 제목 |
Direct synthesis of 2,5-dibutyl furandicarboxylates from galactaric acid |
| 초록 |
2,5-Furan dicarboxylic acid (FDCA) is considered one of the top 12 building block compounds derived from biomass that can lead to a sustainable development of a new chemical platform. In this research, a one-pot synthesis of 2,5-dibutyl furandicarboxylates - a diester of FDCA - was studied. Due to differences in physical properties, 2,5-dibutyl furandicarboxylates are easier to manipulated than FDCA. This can be an advantage for later processes. The synthesis was conducted directly from galactaric acid, also known as mucic acid, with several catalysts and solvents. For the best reaction condition, a study of sufficient catalyst amount and kinetic changes of the main compounds was done. As a result, reaction mechanism and purification method for the interested products was proposed. |
| 저자 |
Huynh Thanh Thien Nhan1, Vanesa Teijeiro Seijas2, 조진구1
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| 소속 |
1한국생산기술(연), 2Univ. of Santiago de Compostela |
| 키워드 |
2; 5 Furandicarboxylic acid (FDCA); galactaric acid; dehydration; esterification
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| E-Mail |
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