화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 Korea-Australia Joint Symposium: Next Generation Polymer Science and Technology (English)
제목 Ultrasonic Chemical Reactions for Carbon-Heteroatom Bond formation and Conjugated Microporous Polymer
초록 Here I will describe a simple and ultrafast method to form C-N or C-O, in various carbon nanomaterials including activated carbon, carbon nanotubes, and graphene, by ultrasonic chemical reaction and then fabricate it binder-free energy storage system. In addition, this ultrasonic chemistry can expand into synthesis of conjugated microporous polymer materials to overcome processing challenges related to these materials and then apply it supercapacitors in-situ. Ultrasonic chemistry simultaneously achieves oxidative C–C coupling polymerization and fabrication of thin films. The reaction yield, porosity, and capacitance of the prepared CMP films were strongly dependent on the applied ultrasonic frequency (120 and 180 kHz). Furthermore, USC was used to prepare highly conductive, 3D porous electrodes by a layer-by-layer sequential deposition of CMPs and single-walled carbon nanotubes.
저자 권태혁
소속 울산과학기술원
키워드 Ultrasonic Chemistry; Carbon-Heteroatom bond; Conjugated Microporous Poymer
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