화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.2113
발표분야 재료
제목 Oxidation Pathway Transition Between Condensed Phase and Gaseous Phase in Nanothermite Composites Using Al Nanoparticles in Three-Dimensionally Ordered Macroporous CuO
초록 In this study, using three dimensionally ordered macroporous (3DOM) CuO and Al nanoparticles (NPs) we established the uniform dispersion thermite system. Elemental mapping images identified that Al and Cu of 3DOM thermite composites are well dispersed all over the structure. Pressurization rate shows volcano type curve as pore diameter increase. We identified this phenomenon is originated from change of combustion mechanism varying with the pore size. After combustion, different aspects of remaining products show that thermite reaction is influenced by condensed and gaseous phase oxygen diffusion. It was found that for improving the thermite performance, it is important to reduce the oxide dimension to the length scale where the gasoues oxygen molecules are depleted.
저자 신도중1, 이도창2
소속 1한국과학기술원, 2KAIST
키워드 화공소재 전반
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