화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 기능성 고분자 (포스터발표만 진행)
제목 Synthesis and characterization of photo-responsive diblock copolymer by ARGET ATRP
초록 A variety of block copolymers composed of Poly(Ethylene Oxide) and Poly(N-isopropyl Acrylamide-co-Coumarine Styrene) segments were synthesized by ARGET ATRP. FT-IR and NMR were used to investigate the chemical structures of the polymers. Molecular weight and PDI was studied by GPC analysis. The as-synthesized block copolymers are able to form micelles with nanosize in aqueous solution as determined by DLS and TEM analyses. In addition, the stabilization of polymer micelles could be controlled through reversible cross-linking of Coumarin moieties under UV-irradiation. The block copolymer micelles with photo-responsive and water-soluble characteristic are expected to be applied in medical science, especially drug delivery system.
저자 장명재, Thanh Binh Mai, 김동우, 임권택
소속 부경대
키워드 ARGET ATRP; Block Copolymer; micelles; Photo; Cross-link
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