| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
MFI-type zeolite coated ceramic tubular membrane in development of divided tubular electrochemical reactor: Efficiency analysis through Co3+homogeneousmediatorgeneration |
| 초록 |
In the present work a tubular MFI-type zeolite coated membrane (TZM) was tested in a plug flow type tubular electrochemical cell for Co2+ oxidation efficiency in high acid medium. Electrolysis of Co2+ was carried out at room temperature (20±3℃) in 4 M H2SO4 at anodic half-cell, and showed 42% Co2+ oxidation with 0.3 V higher cell voltage than the commonly used Nafion324 membrane in planar arrangement. Further, TZM membranes were robust when operated in the cell at different temperatures (10, 30 and 50℃) and current densities as no noticeable change in surface morphology was observable by SEM analysis. A long term test of the TZM at slightly elevated current density (70 mA cm2) showed increased oxidation efficiency of Co2+ to 58% compared to the traditional Nafion324 (43%). |
| 저자 |
문일식, G.MUTHURAMAN
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| 소속 |
순천대 |
| 키워드 |
Zeolite membrane; ceramic membrane; tubular membrane; tubular electrochemical cell; Plug flow electrochemical cell
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| E-Mail |
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