| 학회 | 한국공업화학회 |
| 학술대회 | 2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 | 8권 2호 |
| 발표분야 | 촉매 |
| 제목 | Hydrogen Reduction of Carboxylic Acids over carbon-supported Pd or Ni nanoporous catalysts |
| 초록 | A series of carbon-supported palladium / nickel catalysts was prepared and characterized for various physico-chemical properties. This material is high surface area and chemical stability and hydrophobic nature. Efficient and selective catalytic systems, Ni or Pd on the nanoporous carbon, for the production of TFEA by the hydrogenation of TFAA have been developed. It is found that catalytic activity depends on preparative method, hydrogen pressure, agitation rate, and active species. Hydrogenation of various carboxylic acids and ketones clearly shows the electronic and steric effects on the reaction rates and a plausible reaction mechanism is proposed. |
| 저자 | 이동환1, 이익모1, 김홍곤2 |
| 소속 | 1인하대, 2한국과학기술(연) |
| 키워드 | Hydrogen; catalyst |
