| 초록 |
The development of high-energy and high-power density sodium-ion batteries is a great challenge for modern electrochemistry. The main hurdle to wide acceptance of sodium-ion batteries lies in identifying and developing suitable new electrode materials. We present a composition-graded cathode with average composition Na[Ni0.61Co0.12Mn0.27]O2, which exhibits excellent performance and stability. In addition to the concentration gradients of the transition metal ions, the cathode is composed of spoke-like nanorods assembled into a spherical superstructure. Individual nanorod particles also possess strong crystallographic texture with respect to the center of the spherical particle. Micro-compression tests have explicitly verified the mechanical robustness of the composition-graded cathode and single particle electrochemical measurements have demonstrated the electrochemical stability during Na+-ion insertion and extraction at high rates. |
