| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.100 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis and Characterization of Sulfonated Poly(Phenylene Sulfide Sulfone Nitrile) for Direct Methanol Fule Cell Applications |
| 초록 |
High molecular weight sulfonated poly(phenylene sulfide sulfone nitrile) (SPSSN) with various degrees of sulfonation (DS) were prepared by polycondensation of monomers in N-methyl-2-pyrrolidone. The chemical structures of SPSSNs were confirmed by FT-IR and 1H NMR spectroscopy. SPSSN membranes with DS lower than 50% show relatively higher oxidative stability than any other sulfonated poly(arylene ether)s. Furthermore, SPSSN membranes exhibit improved methanol barrier property and proton conductivity as compared with Nafion membrane. Consequently, the membrane-electrode assemblies based on SPSSN membranes show excellent electrochemical DMFC performances at high temperature of 90 oC. |
| 저자 |
푸동상, 이소영, 이창현, 이영무
|
| 소속 |
한양대 |
| 키워드 |
fuel cells; proton conductivity; sulfonated poly(phenylene sulfide sulfone nitrile)
|
| E-Mail |
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| 원문파일 |
초록 보기 |
