화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 고분자합성
제목 Merrifield resin modified by polyhydroxystyrene and polytrihydroxystyrene moiety using RAFT polymerization for metal ion trapper 
초록 Catechol and gallol group has a high binding affinity towards metal ions through metal ion coordination and hydrogen bonding. Here, we focus on functionalizing the appropriate commercial resin to make high-performance heavy metal ion absorbers. So, first time, we synthesized dihydroxystyrene and trihydroxy styrene polymer on the surface of Merrifield's resins using the reversible addition−fragmentation chain-transfer (RAFT) polymerization followed by the reduction method. In the RAFT method, we can enhance the functional group on the surface area based on monomer insertion on resin during polymerization. We investigated the removal capacity of lead, copper, zinc, magnesium, and silver ions from the aqueous solution. The polymerization yields were quantitative.
저자 Avnish Kumar Mishra1, 이은지2
소속 1GIST, 2광주과학기술원
키워드 polydihydroxystyrene; polytrihydroxystyrene; Merrifield resin; metal adsorption/desorption; reversible addition–fragmentation chain transfer polymerisation; polymer purification
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