| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
The Kinetics of Copolymerization of Vinylidene Fluoride with Hexafluoropropylene using lauroyl peroxide as an initiator |
| 초록 |
In a previous study, we reported the kinetics of the radical copolymerization of VDF with HFP using diisopropylperoxy dicarbonate (DIPPDC) as an initiator in 1,1,2-trichlorotrifluoroethane (R-113) solvent. We obtained monomer reactivity ratios(rVDF=1.71, rHFP=0) and monomer-polymer composition diagram of VDF-HFP using the fineman and ross method. In this study, we introduce the kinetics of solution radical copolymerization using lauroyl peroxide as an initiator. A kinetic approach enabled us to assess the reactivity ratios of both co-monomers. In addition, the microstructure and the thermal properties of these fluorocopolymers have been investigated. |
| 저자 |
이상구1, 하종욱1, 박인준1, 이수복1, 이종대2
|
| 소속 |
1한국화학(연), 2충북대 |
| 키워드 |
vinylidene fluoride; hexafluoropropylene; solution radical polymerization
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| E-Mail |
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