| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Various Methacrylate Polymers by Using Hyperbranched Polyglycidols-terminated 2,2,6,6-tetramethyl-1-piperidinyloxy Nitroxide |
| 초록 |
Poly(2-hydroxyethyl methacrylate) (PHEMA) is a biocompatible methacrylate polymer widely used for biomedical applications. Like HEMA, several methacrylate type of polymers have adequate biocompatibility. Various methacrylate monomers can be polymerized by nitroxide-terminated polymerization (NMP) using hyperbranched polyglycidols-terminated 2,2,6,6-tetramethyl-1-piperidinyloxy nitroxide (TEMPO). As initiator for NMP, hyperbranched polyglycidols-terminated TEMPO is synthesized via click chemistry using hyperbranched polglycidols that partially modified with azide group and 4-alkynyl TEMPO modified from 4-hydroxy TEMPO. NMP process using methacrylate monomer would be controlled by extent of modification of hydroxyl group in HBP or structure and molecular weight of HBP. |
| 저자 |
허민선, 김일
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| 소속 |
부산대 |
| 키워드 |
Nitroxide-mediated polymerization; Click chemistry; Hyperbranched polyglycidol
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| E-Mail |
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