| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Synthesis of biomass-based amines: Metal-free catalytic reductive amination of xylose using Pyridine-based ionic liquid/Triethoxysilane |
| 초록 |
Dehydration of biomass into valuable nitrogen-containing compounds is highly desired, such a process remains challenging. The synthesis of amines (furfurylamines) from xylose utilizing [Pro(Etpy)3][Lac]3 ionic liquid (IL) with Eto3SiH as a reductive agent, which offers a metal-free route and mild condition. This IL showed excellent catalytic activity toward the synthesis of industrially important molecules. Dehydration of xylose followed by reductive amination gave 63-72% yield of furfurylamines with 100% purity using [Pro(Etpy)3][Lac]3 IL catalyst with Eto3SiH. This one pot three-step procedure is highly efficient for the synthesis of furfurylamines from xylose as it avoids isolation of furfural and requires single catalysts for three different steps. Additionally, this IL demonstrates good recyclability and effectivity. |
| 저자 |
Rathod Pramod Vithal, 김 헌
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| 소속 |
명지대 |
| 키워드 |
Biomass; Xylose; Furfural; Triethoxysilane; Ionic Liquid
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| E-Mail |
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