화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2009년 가을 (10/15 ~ 10/16, 서울산업대학교 내 서울테크노파크)
권호 13권 2호
발표분야 정밀화학(포스터)
제목 Synthesis and Characterization of New Ni(II) Complex of the Pentaaza Noncyclic ligand 5-Methyl-1,2,8,9-dicyclohexano-3,5,7-triazanonane-1,9-diamine
초록 Recently, various new types of sterically congested cyclam derivatives have been synthesized and some very versatile chemistry of their nickel complexes have been studied. For example, the macrocyclic ligand 1[1] and 2[2] have been prepared from 1,3-dibromopropane for 1 and methylvinylketone for 2 with cyclohexane 1,2-diamine. However, most of them were tetraaza macrocycles with cyclohexane rings obtained by nontemplate reactions, and two methyl pendant arms at the uncoordinated nitrogen atom(6 and 13 positions of cyclam) in the fully saturated 14 membred macrocyclic backbone, by template condensation reactions have not been reported to data.
저자 임운식, 김성권, 채규윤
소속 원광대
키워드 Ni(II) Complex
E-Mail