| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 |
18권 1호 |
| 발표분야 |
차세대전지의 전기화학적원리 II |
| 제목 |
Morphological rearrangement of ionic channels in solid state disulfonated poly(arylene ether) copolymers via direct fluorination |
| 초록 |
Disulfonated poly(arylene ether sulfone) random and multiblock copolymers with the same chemical architecture state were physicochemically tuned in solid membrane via direct fluorination under a dilute fluorine (F2)-nitrogen (N2) mixture, which was expected to minimize chemical degradation by a highly reactive F2 gas. The direct fluorination and subsequent acidification enabled C-H bonds of aromatic rings in hydrophobic domains or blocks of the copolymers to be selectively converted into C-F bonds. Interestingly, the direct fluorination on the copolymer membranes influenced their morphologies and water/ion transport properties in different ways, even though both sulfonic acid level and swelling ratio of the precursor copolymers were similar. |
| 저자 |
이창현1, 이관수2, Mingqiang Zhang2, James E. McGrath2, Robert B. Moore2, Mark D. Lingwood2, Louis A. Madsen2, 위성술3, 이소영4, 이영무4
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| 소속 |
1단국대, 2버지니아텍, 3National Magnetic Field Laboratory, 4한양대 |
| 키워드 |
직접불소화; 이온재정렬; 연료전지; 수처리; 삼투발전
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| E-Mail |
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