| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Lactate-based ionic liquid catalyzed reductive amination of biomass-Derived aldehyde/ketones and xylose |
| 초록 |
Conversion of biomass into valuable nitrogen-containing compounds is highly desired, however, such a process remains challenging. Here we present lactate based ionic liquid catalyzed reductive amination using triethoxysilane as a reductive agent, which provides a metal-free route one–post synthesis of furfuryl amine from xylose under mila conditions. This catalyst shows excellent catalytic activity toward the synthesis of industrially important furfuryl amine from furfural or biomass-Derived aldehydes/ketones and xylose. Reduction of aldehydes/ketones proceeded in 75-96 % yield, and dehydration of xylose followed by reduction gave 55-70 % yield of furfuryl amine using IL catalyst and triethoxysilane. The one-pot three-step procedure is highly efficient for synthesis of furfuryl amine from xylose as it avoids isolation of furfural and requires a single catalyst for three different steps. The reaction conditions are mild and avoid the use of, Nobel metal and transition metal catalysts. |
| 저자 |
Rathod Pramod Vithal, 김 헌
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| 소속 |
명지대 |
| 키워드 |
Furfurylamines; Xylose; Biomass-Derived aldehydes/ketones and Ionic Liquid.
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| E-Mail |
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