| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 | 25권 1호, p.930 |
| 발표분야 | 촉매 및 반응공학(Catalysis and Reaction Engineering) |
| 제목 | Effects of metal promoters on mesoporous Zr-incorporated Fe2O3 catalyst for CO2 hydrogenation |
| 초록 | Among typical COx hydrogenation reactions, Fischer-Tropsch synthesis (FTS) reaction has been well-known to transform syngas to a wide range of hydrocarbons. In our previous studies, the ZrO2 incorporated mesoporous Fe2O3 showed an improved catalytic activity and stability. In the present study, CO2 hydrogenation was applied to verify the various chemical promoters such as Pt, Ru, and Mn on the highly ordered mesoporous ZrO2-Fe2O3. The metal-promoted FTS catalysts showed an enhanced catalytic activity by increasing the reducibility of the active Fe2O3 to form active iron carbides preferentially. In order to characterize the effects of the metal promoters on the ordered mesoporous ZrO2-Fe2O3, powder X-ray diffraction (XRD), temperature-programmed reduction (H2-TPR), N2 physisorption analysis, and X-ray Photoelectron Spectroscopy (XPS) were carried out. Keywords : mesoporous Fe2O3; metal promoters; CO2 hydrogenation; structure stability; enhanced activity and selectivity. |
| 저자 | 조재민, 배종욱 |
| 소속 | 성균관대 |
| 키워드 | 촉매 |
| 원문파일 | 초록 보기 |
