화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터)
권호 28권 1호, p.573
발표분야 [주제 8] 에너지 저장
제목 Efficient and stable electrocatalyst based on 2D conductive bimetallic metal -organic framework towards overall water splitting
초록 Developing electrocatalysts with high activity and durability has been an ongoing target for electrolyzer water, which is particularly significant for renewable hydrogen energy production. In this study, Fe/Zn bimetal-organic framework (FexZn2-x(HAB)2MOF) has been prepared using hexaaminobenzenes (HAB) as an organic linker viz a solvothermal and exfoliation process. They exhibited excellent electrochemical performance because of the directional electron transport and synergistic effects of divalent metals and the simple preparation strategy. Among them, Fe/Zn-HAB-60 displayed high catalytic activity with a low overpotential 226 mV at 10 mA cm-2 for the OER and 120 mV at 10mA cm-2 for the HER. The divalent atoms interaction possibly boosted the intrinsic 4e-/2e- of the OER/HER activity and stability.
저자 Tran Van Phuc1, Ravi Nivetha2, Huynh Ngoc-Diem2, Jana Jayasmita2, 허승현1
소속 1울산대, 2Univ. of Ulsan
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