| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
국제협력위원회 -그린에너지와 나노화학 |
| 제목 |
Mechanism of Catalyst-life Lost and Activity Regeneration of ZSM-5 Catalysts in DTO Reaction |
| 초록 |
Regeneration of H-ZSM-5 catalyst was tested on DME conversion to olefin. The catalyst life was stabilized by the regeneration for a number of reactions. Since the decreases in both acid amount and surface area were observed, the regeneration must cause the change of structure, that is, dealumination. To confirm this assumption, dealuminated H-ZSM-5 was synthesized by steaming treatment so that the catalyst life was prolonged. The dealumination from zeolite framework was made progress via the formation "unstable Al species" and the their change to extra-framework. |
| 저자 |
Atsushi MURAMATSU1, Masafumi NAKAYA2, Yuchiro YAMAZAKI3
|
| 소속 |
1Institute of Multidisciplinary Research for Advanced Material, 2Tohoku Univ., 3Japan |
| 키워드 |
DME to olefin; H-ZSM-5; Dealumination; Activity
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| E-Mail |
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