화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.3187
발표분야 열역학
제목 Phase Behavior for the Binary System Carbon Dioxide + Neopentyl Glycol Diacrylate Mixture: Experimental Measurements and Modeling with a Cubic Equation of State
초록 Phase behavior data for the binary mixture of (carbon dioxide + neopentyl glycol diacrylate) system were measured at (313.2, 333.2, 353.2, 373.2 and 393.2) K and pressures up to 24.52 MPa. The carbon dioxide + neopentyl glycol diacrylate system has continuous critical mixture curve that exhibit maximums in pressure at temperatures between the critical temperatures of carbon dioxide and neopentyl glycol diacrylate. The solubility of neopentyl glycol diacrylate for the (carbon dioxide + neopentyl glycol diacrylate) system increases as the temperature increase at constant pressure. The (carbon dioxide + neopentyl glycol diacrylate) mixture exhibit type-I phase behavior. The experimental result for (carbon dioxide + neopentyl glycol diacrylate) mixture is correlated with Peng-Robinson equation of state using a van der Waals one-fluid mixing rule including two adjustable parameters.
저자 변헌수1, 류 상1, 김성현1, 윤순도1, 유기풍2
소속 1전남대, 2서강대
키워드 Phase behavior; Carbon dioxide + neopentyl glycol diacrylate; cubic equation of state;
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