학회 |
한국화학공학회 |
학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
권호 |
21권 1호, p.1120 |
발표분야 |
촉매 및 반응공학 |
제목 |
Autothermal reforming properties of nickel-alumina based catalysts with n-hexadecane |
초록 |
To investigate ATR (autothermal reforming) properties for diesel, various Ni-Al based catalyst added with Lanthanum (LaNA10-PM), Cerium (CeNA10-PM) and Iron (FeNA10-PM) promoter were prepared. These catalysts were prepared by polymer incipient method using PMMA (poly methyl methacrylate). The catalytic activity of the catalysts was tested carried out in a fixed-bed reactor, S/C = 1.19, O2/C = 2.42 and GHSV = 5000~12000 h-1 at 750 ℃. N-hexadecane was selected as a surrogate for diesel fuel because it is regarded to have similar properties. The FeNA10-PM catalyst showed the higher and more stable H2, CO yields and hexadecane conversion than other catalysts. The catalysts were characterized by XRD, XPS and SEM-EDS. |
저자 |
하동수, 최성민, 임은지, 정석용, 이수출, 김재창
|
소속 |
경북대 |
키워드 |
autothermal reforming; n-hexadecane; nickel-alumina
|
E-Mail |
|
원문파일 |
초록 보기 |