| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Synthesis and characterization of new green phosphorescent polymers bearing a bis(2-phenylpyridine)iridium(III)(dibenzoylmethane) complex |
| 초록 |
Two series of new green phosphorescent polymers bearing a bis(2-phenylpyridine)iridium(III)(dibenzoylmethane) [(ppy)2Irdbm] complex were designed and synthesized. The two different host polymers for the synthesized iridium complex were polycarbazole (PCbz) derivatives or polyfluorene with pendant carbazole groups (PFCbz). The iridium complex monomer was copolymerized with the two host monomers using varying monomer ratios via a Yamamoto coupling reaction. Electroluminescent devices with the configuration ITO/PEDOT:PSS/polymer/BmPyPB/LiF/Al were fabricated and characterized. The phosphorescent polymers composed of the iridium complex guest and polyfluorene with carbazole pendants as a host performed better than the polymers composed of the same guest and the main chain polycarbazole host. A maximum external quantum efficiency of 0.73%, a luminous efficiency of 1.21 cd/A, and a maximum luminance of 372 cd/m2 were obtained. |
| 저자 |
XU FEI1, 김희운1, 미동보1, 황주현2, 이정익3, 황도훈1
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| 소속 |
1부산대, 2정자통신(연), 3전자통신(연) |
| 키워드 |
carbazole; iridium(III) complex; phosphorescent polymer light-emitting devices
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| E-Mail |
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