| 학회 |
한국고분자학회 |
| 학술대회 |
2004년 봄 (04/09 ~ 04/10, 고려대학교) |
| 권호 |
29권 1호, p.80 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of Poly(arylene ether amine)s through Nucleophilic Aromatic Substitution Reaction (SNAr) |
| 초록 |
Poly(arylene ether)s usually have been prepared via SNAr reaction of activated dihalo- or dinitro-substituted monomers and diols, because the oligomeric polymers are obtained with unactivated monomer systems even at high temperature and long reaction time. In this research, poly(arylene ether)s containing aromatic amine units were synthesized via nucleophilic aromatic substitution reaction of the novel monomer, bis(4-nitro-3-trifluoromethylphenyl)phenylamine and bis(4-fluoro-3-trifluoromethylphenyl)amine, with several bisphenols. Hyperbranched poly(arylene ether amine)s were also synthesized by one step polymerization of the novel monomer, 4-[bis(4-nitro-3-trifluoromethylphenyl)amino]phenol. Even though the monomer has diphenylamine or triphenylamine group which is a deactivating group for SNAr reaction, the polymerization proceeded successfully. It seems that the electron-withdrawing effect of trifluoromethyl group at the ortho position of the leaving groups is large enough to suppress the negative effect of the amine group. The detailed reaction behavior and properties of polymers will be discussed. |
| 저자 |
이몽섭1, 김윤준2, 서명은1, 정유영2, 김상율1
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| 소속 |
1한국과학기술원 화학과, 2분자과학사업단 (BK21) & 기능성 고분자 연구센터 |
| 키워드 |
poly(arylene ether)s; triphenylamine; diphenylamine; nucleophilic aromatic substitution reaction
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| E-Mail |
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