학회 |
한국고분자학회 |
학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
권호 |
37권 1호 |
발표분야 |
분자전자 부문위원회 |
제목 |
Synthesis and characterization of water-soluble fullerene derivatives as interfacial materials for organic solar cells |
초록 |
Interface engineering in organic solar cells is one of the strategies for high performance devices. Recently, fullerene derivatives for inverted organic solar cells have been studied due to their high electron mobility, tunable energy level and improvement of electrical contact. Especially, water-soluble fullerene derivatives as interfacial layer have some advantages; water solubility, well-matched energy level by induced interface dipoles and accomplishment of tandem cells. In this study, we synthesized water-soluble fullerene derivative having amine groups with high-yield amination reaction methods. The synthesized amino fullerene can be dissolved in polar solvent, preventing intermixing of the multilayers. The structural, optical, thermal and electronic properties of the fullerene derivative was characterized by 1H-NMR, UV-vis spectroscopy, TGA/DSC and Kelvin probe measurement. Finally, the effects of using the interfacial layer in the organic solar cells will be discussed. |
저자 |
이세현1, 김동유1, 윤진문2, 유병관3, 이승훈1, 강리라1
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소속 |
1광주과학기술원 신소재공학부, 2나노바이오재료전자공학과, 3광공학응용물리학과 |
키워드 |
fullerene; interfacial; solar cell; buffer layer
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E-Mail |
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